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dc.contributorUniversitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
dc.contributorUniversitat Politècnica de València. Departamento de Química - Departament de Química
dc.contributor.authorNafria, Raquel
dc.contributor.authorRamirez de la Piscina, Pilar
dc.contributor.authorHoms, Narcis
dc.contributor.authorRamon Morante, Joan
dc.contributor.authorCabot, Andreu
dc.contributor.authorDÍAZ MORALES, URBANO MANUEL
dc.contributor.authorCorma Canós, Avelino
dc.date.accessioned2019-10-22T10:49:55Z
dc.date.available2019-10-22T10:49:55Z
dc.date.created2016-06-29 01:08
dc.date.issued2013
dc.identifieroai:riunet.upv.es:10251/66100
dc.identifierurn:issn:0959-9428
dc.identifierhttp://hdl.handle.net/10251/66100
dc.identifierinfo:doi:10.1039/c3ta13346j
dc.identifier.urihttp://hdl.handle.net/20.500.12424/691643
dc.description.abstractThe ability to produce catalytic nanoparticles with controlled properties is key to developing and producing heterogeneous catalysts with optimized activity and selectivity. No less important is to maximize the nanoparticle dispersion over high area supports maintaining their optimized properties. Here we detail a general procedure to produce heterogeneous catalysts containing a large surface area mesoporous support and highly dispersed catalytic nanoparticles with controlled properties. We exemplify the developed method using colloidal gold nanocrystals as the catalytically active phase and titanium oxide as the paradigmatic support. Our synthetic strategy is based on the growth of an inorganic organic hybrid mesoporous material from the surface of the colloidal nanocrystals. A variety of organic spacers allows tuning the final porosity of the support. The good accessibility of the active catalytic sites in these materials is demonstrated by high CO oxidation conversion values.
dc.description.abstractEuropean Regional Development Funds
dc.description.abstractSpanish MICINN projects CSD2009-00050
dc.description.abstractSpanish MICINN projects MAT2011-29020-C02-01
dc.description.abstractSevero Ochoa Excellence Program SEV-2012-0267
dc.description.abstractNafria, R.; Ramirez De La Piscina, P.; Homs, N.; Ramon Morante, J.; Cabot, A.; Díaz Morales, UM.; Corma Canós, A. (2013). Embedding catalytic nanoparticles inside mesoporous structures with controlled porosity: Au@TiO2. Journal of Materials Chemistry. 1(45):14170-14176. doi:10.1039/c3ta13346j.
dc.description.abstractSenia
dc.description.abstract14170
dc.description.abstract14176
dc.description.abstract1
dc.description.abstract45
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofJournal of Materials Chemistry
dc.relation.ispartofhttp://dx.doi.org/10.1039/c3ta13346j
dc.relation.ispartof254887
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectCoated Gold Nanoparticles
dc.subjectSurface-Area
dc.subjectCo Oxidation
dc.subjectSupported Gold
dc.subjectPorous Silica
dc.subjectSba-15 Silica
dc.subjectNanocrystals
dc.subjectAu/Tio2
dc.subjectSio2
dc.subjectSpectroscopy
dc.subjectQUIMICA ORGANICA
dc.titleEmbedding catalytic nanoparticles inside mesoporous structures with controlled porosity: Au@TiO2
dc.typeinfo:eu-repo/semantics/article
ge.collectioncodeOAIDATA
ge.dataimportlabelOAI metadata object
ge.identifier.legacyglobethics:10212954
ge.identifier.permalinkhttps://www.globethics.net/gel/10212954
ge.lastmodificationdate2016-06-29 01:08
ge.lastmodificationuseradmin@pointsoftware.ch (import)
ge.submissions0
ge.oai.exportid148650
ge.oai.repositoryid5905
ge.oai.setnameInvestigación
ge.oai.setnameArtículos, conferencias, monografías
ge.oai.setnameOpen Access DRIVERset
ge.oai.setspeccom_10251_11198
ge.oai.setspeccol_10251_3829
ge.oai.setspecdriver
ge.oai.streamid2
ge.setnameGlobeEthicsLib
ge.setspecglobeethicslib
ge.linkhttp://hdl.handle.net/10251/66100


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